刘小明团队

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团队名称 绿色功能材料与应用团队

联系方式 xiaoming.liu@mail.zjxu.edu.cn; xiaoming.liu@ncu.edu.cn

0573-83643937 / 15858311808

团队网页:http://cbcse.zjxu.edu.cn/xliu/

团队介绍

科研团队的负责人是浙江省钱江高级人才特聘教授刘小明博士,研究领域包括仿生催化、生物无机化学、过渡金属配位催化等带领团队承担各类研究项目17项(其中国家级课题8项)。在国际著名期刊上发表SCI研究论文110多篇、获授权专利11项,出席国内外学术会议50余次。已培养博士研究生3名,硕士研究生近50名。本团队还吸引了大量的本科学生进入实验室参与教师的研究工作,自2015年以来,共有24名学生在省化学竞赛中获得一等奖。

团队详细情况请见主页http://cbcse.zjxu.edu.cn/xliu/

主要研究领域

1. 仿生催化主要围绕催化放氢的新体系和催化机理开展研究工作。

2. 生物无机化学:基于铁羰基化合物的一氧化碳释放剂研究释放方法、释放动力学和释放机理),并与第一附属医院泌尿外科的何屹主任医生团队开展一氧化碳释放在肾脏手术中的应用研究;其它过渡金属配合物及其细胞毒性和构效关系研究。

3. 过渡金属配位催化:铜铁等过渡金属催化体系(配合物均相催化、氧化物表面配位催化)催化空气选择性醇氧化研究。

社会服务领域:

本团队在做好教学工作、应用基础研究的同时,围绕聚氨酯、微电子化学前驱体和高品质纺织油剂的研发和应用,与嘉兴禾大科技股份有限公司、安徽博泰电子材料有限公司、桐乡市金羊皮革化工有限公司等企业深入开展产学研合作、共同开展应用型人才培养,共计在研横向项目3项,经费130万。

代表性成果(论文、专利与获奖)

1. Yunlian Yang, Wei Zhong, Ruonan Ma, Chunxin Lu, Zhongquan Shen, Xiaoming Liu* Shuhua Zhang* and Hongming Wang*, Engineering the surface of cuprous oxide via surface coordination for efficient catalysis on aerobic oxidation of benzylic alcohols under ambient conditions, Appl. Surf. Sci., 2021. 543, 148840.

2. Xiujuan Jiang, Zhiyin Xiao, Wei Zhong, Xiaoming Liu*, Brief survey of diiron and monoiron carbonyl complexes and their potentials as CO-releasing molecules (CORMs), Coord. Chem. Revs., 2021, 429, 213634.

3. Zhiyin Xiao, Natarajan Mookan, Wei Zhong, Xiaoming Liu*, Probing into the electrochemistry of four nickel(II) and cobalt(II) complexes with azadiphosphine ligands (PNP) and their catalysis on proton reduction. Electrochim. Acta, 2020, 340, 135998.

4. Wei Zhong*, Li Wu, Weidong Jiang, Yulong Li, Natarajan Mookan, Xiaoming Liu*. Proton-coupled electron transfer in the reduction of diiron hexacarbonyl complexes and its enhancement on the electrocatalytic reduction of protons by a pendant basic group. Dalton Trans., 2019, 48, 13711–13718.

5. Bingying Rong, Wei Zhong*, Erxing Gu, Li Long, Lijuan Song*, Xiaoming Liu*, Probing the electron transfer mechanism of the half-sandwich iron(II)-carbonyl complexes and their catalysis on proton reduction, Electrochim. Acta, 2018, 283, 2735.

6. Jun Ou, Weihua Zheng, Zhiyin Xiao, Yuping Yan, Xiujuan Jiang, Yong Dou, Ran Jiang and Xiaoming Liu*, Core-shell materials bearing iron (II) carbonyl units and their CO-release via upconversion process, J. Mat. Chem. B., 2017, 5, 8161–8168.

7. Wei Zhong, Zhiyin Xiao, Guifen Qian, Xiaoming Liu*, The influence of a peripheral functional group of diiron hexacarbonyl complexes on their electrochemistry and electrocatalytic reduction of proton, Electrochim. Acta, 2017, 247, 779–786.

8. Xinglong Zhu, Wei Zhong, Xiaoming Liu*, Polymers functionalized with 1,2-benzenedithiolate-bridged model compound of [FeFe]-hydrogenase: synthesis, characterization and their catalytic activity, Int. J. Hydrogen Energy, 2016, 41, 14068–14078.

9. Xiujuan Jiang, Limei Chen, Xiu Wang, Li Long, Zhiyin Xiao and Xiaoming Liu*, Photoinduced Carbon Monoxide Release from Half-Sandwich Iron(II) Carbonyl Complexes by Visible Irradiation: Kinetic Analysis and Mechanistic Investigation, Chem. Eur. J., 2015, 21, 13065-13072.

10. Guifen Qian, Hailong Wang, Wei Zhong and Xiaoming Liu*, Electrochemical investigation into the electron transfer mechanism of a diiron hexacarbonyl complex bearing a bridging naphthalene moiety, Electrochim. Acta, 2015, 163, 190-195.

11. Xiujuan Jiang, Li Long, Hailong Wang, Limei Chen, Xiaoming Liu*, Diiron hexacarbonyl complexes as potential CO-RMs: their CO-releasing initiated by the substitution reaction with cysteamine and structural correlation to the bridging linkage, Dalton Trans., 2014, 43, 9968–9975.

12. Li Long, Xiujuan Jiang, Xiu Wang, Zhiyin Xiao, Xiaoming Liu*, Water-soluble diiron hexacarbonyl complex as a CO-RM: controllable CO-releasing, releasing mechanism and biocompatibility, Dalton Trans., 2013, 42, 15663–15669.

13. Li Long, Zhiyin Xiao, Giuseppe Zampella*, Zhenhong Wei, Luca De Gioia, Xiaoming Liu*, The reactions of pyridinyl thioesters with triirondodecacarbonyl: their novel diiron carbonyl complexes and mechanistic investigations, Dalton Trans., 2012, 41, 9482–9492.

14. Xiufeng Wang, Zhimei Li, Xirui Zeng, Qiuyan Luo, David J. Evans, Christopher J. Pickett*, Xiaoming Liu*, The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(II) or low-spin Fe(0)? Chem. Commun., 2008, 3555-3557.

15. Cédric Tard, Xiaoming Liu, Saad K. Ibrahim, Maurizio Bruschi, Luca De Gioia, Sian Davies, Xin Yang, Lai-Sheng Wang and Christopher J. Pickett*, Synthesis of the H-Cluster Framework of Iron-Only Hydrogenase, Nature, 2005, 433, 610-613.

16. 刘小明;顾二形;姜秀娟;肖志音,水溶性铁羰基类化合物及其制备方法和应用,专利号:ZL201810621364.X。授权日期:20210105,专利证书号:第4190070号。

17. 沈忠权;刘小明;钟伟;王儒杰,皮革软化剂及其制备方法,专利号:ZL 201810565983.1。授权日期:20201211,专利证书号:第4146108号。

18. 刘小明;姜秀娟;陈丽梅;张佳瑶;龙莉,一种促进一氧化碳释放剂释放一氧化碳并防止形成沉淀的方法,专利号:ZL01510180597.7授权日期:20171226专利证书号:2754331号。

19. 钟伟;刘小明,一种制备邻苯二硫酚的方法,专利号:ZL201510212276.0。授权日期:20160824日,专利证书号:第2210018号。

20. 姜秀娟;刘小明;龙莉;肖志音;曾艳,一种水溶性铁羰基化合物及其制备方法和应用,专利号:ZL 201210175853.X。授权日期:20150114日,专利证书号:第1565669号。



 



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