个人简介

博士，讲师，硕士生导师，2016年毕业于浙江大学高分子系获学士学位。并于2021年获博士学位，后进入嘉兴学院工作。主要从事开环聚合与计算化学研究工作，研究方向包括（1）聚氨基酸合成、机理分析；（2）稀土催化开环聚合；（3）反应机理、各类材料性质计算。

目前在国内外学术刊物上发表SCI论文30余篇，累计被引超过1000次，h因子16。以第一作者或共同第一作者在Adv. Mater., Nat. Commun.、 Macromolecules等期刊上发表论文10篇，在Front. Chem.发表邀请综述1篇。主持国家科学基金青年基金一项（在研）、参与国家科学基金面上项目两项。

学术主页：https://scholar.google.com.hk/citations?user=9PoFyxAAAAAJ

ORCiD: https://orcid.org/0000-0003-1033-9756

Email: baitw@zjxu.edu.cn  地址：明礼楼527

主讲课程

计算机辅助分子合成与设计、医药文献检索与专利、工程图学、工程图学（英）

研究关键词

聚氨基酸、稀土催化剂、开环聚合、计算化学

代表论文

[37]     Zhang, J.,# Bai, T.,# Liu, W.,# Li, M., Zang, Q., Ye, C., Sun, J. Z., Shi, Y., Ling, J., Qin, A., All-organic polymeric materials with high refractive index and excellent transparency. Nature Communications, 2023, 14(1): 3524.

[36]     Yin, S., Qu, J., Kannan, P., Lu, L., Zhou, F., Linkov, V., Bai, T., Cao, H., Wang, P., Ji, S., Indium/cobalt nanoparticles impregnated porous nitrogen-doped carbon matrix as a 3D sulfur host for lithium polysulfide adsorption-desorption and catalytic conversion in lithium-sulfur batteries. Composites Part B: Engineering, 2023, 264: 110905.

[35]     Wang, X., Lin, Y., Sun, X., Wu, Y., Miao, H., Chu, J., Bai, T., Fu, Y., A lysosomal targeted fluorescent probe based on BODIPY for monitoring NO in living cells and zebrafish imaging. Sensors and Actuators B: Chemical, 2023, 383: 133592.

[34]     Zhao, Y., Bai, T., Liu, Y., Lv, Y., Zhou, Z., Shen, Y., Jiang, L., Encapsulation of volatile monoterpene fragrances in mesoporous organosilica nanoparticles and potential application in fruit preservation. Nanomaterials, 2022, 13(1): 104.

[33]    Song, B., Bai, T., Liu, D., Hu, R., Lu, D., Qin, A., Ling, J., Tang, B. Z., Visualized degradation of CO2-based unsaturated polyesters toward structure-controlled and high-value-added fluorophores. CCS Chemistry, 2022, 4(1): 237-249.

[32]     Chen, K., Zhu, Z., Bai, T., Mei, Y., Shen, T., Ling, J., Ni, X., A Topology‐Defined Polyester Elastomer from CO2 and 1, 3‐Butadiene: A One‐Pot‐One‐Step “Scrambling Polymerizations” Strategy. Angewandte Chemie, 2022, 134(46): e202213028.

[31]     Cai, Q., Bai, T., Zhang, H., Yao, X., Ling, J., Zhu, W., Catalyst-free synthesis of polyesters via conventional melt polycondensation. Materials Today, 2021, 51: 155-164.

[30]     Zhu, C. N.,# Bai, T.,# Wang, H., Ling, J., Huang, F., Hong, W., Zheng, Q., Wu, Z. L., Dual-Encryption in a shape-memory hydrogel with tunable fluorescence and reconfigurable architecture. Advanced Materials, 2021: 2102023. (https://doi.org/10.1002/adma.202102023)

[29]     Bai, T., Zheng, B., Ling, J., DFT studies on the synthesis of poly(α-amino acid)s via the amine-mediated ring opening polymerizations of N-carboxyanhydrides and N-thiocarboxyanhydrides. Frontiers in Chemistry, 2021, 9: 134.

[28]     Bai, T., Zhou, P., Li, Z., Zheng, B., Ling, J., Seeding crystals, harvesting polypeptides: Preparing long chiral-sequence controlled polypeptides by interlocked polymerization in cocrystals (iPiC) of N-thiocarboxyanhydride (NTA) at room temperature. Macromolecules, 2021, 54(14): 6691-6697.

[27]     Bai, T., Shen, B., Cai, D., Luo, Y., Zhou, P., Xia, J., Zheng, B., Zhang, K., Xie, R., Ni, X., Understanding ring-closing and racemization to prepare α-amino acid NCA and NTA monomers: A DFT study. Physical Chemistry Chemical Physics, 2020, 22(26): 14868-14874.

[26]     Bai, T., Ni, X., Ling, J., Shen, Z., Mechanism of Janus polymerization: A DFT study. Chinese Journal of Polymer Science, 2019, 37(10): 990-994.

[25]     Bai, T., Ling, J., Polymerization rate difference of N‐alkyl glycine NCAs: Steric hindrance or not? Biopolymers, 2019, 110(4): e23261.

[24]     Song, B.,# Bai, T.,# Xu, X., Chen, X., Liu, D., Guo, J., Qin, A., Ling, J., Tang, B. Z., Multifunctional linear and hyperbranched five-membered cyclic carbonate-based polymers directly generated from CO2 and alkyne-based three-component polymerization. Macromolecules, 2019, 52(15): 5546-5554.

[23]     Bai, T., Ling, J., NAM-TMS mechanism of α-amino acid N-carboxyanhydride polymerization: A DFT study. The Journal of Physical Chemistry A, 2017, 121(23): 4588-4593.

[22]     Yu, H., Tong, Z., Bai, T., Mao, Z., Ni, X., Ling, J., Self‐crosslinked poly‐L‐ornithine and poly‐L‐arginine networks: Synthesis, characterization, pH‐responsibility, biocompatibility, and AIE‐functionality. Journal of Applied Polymer Science, 2021, 138(32): 50802.

[21]    Song, B., Bai, T., Liu, D., Hu, R., Lu, D., Qin, A., Ling, J., Tang, B. Z., Visualized degradation of CO2-based unsaturated polyesters toward structure-controlled and high-value-added fluorophores. CCS Chemistry, 2021: 499-511.

[20]     Zheng, B., Bai, T., Ling, J., Sun, J., Direct N-substituted N-thiocarboxyanhydride polymerization towards polypeptoids bearing unprotected carboxyl groups. Communications Chemistry, 2020, 3(1): 1-9.

[19]     Qiu, H., Shah, M. I., Bai, T., Jiang, L., Ling, J., Zwitterionic copolymerization of γ-butyrolactone with 3,3-bis(chloromethyl)oxacyclobutane catalyzed by scandium triflates. Polymer Chemistry, 2020, 11(11): 1845-1851.

[18]     Chen, X., Bai, T., Hu, R., Song, B., Lu, L., Ling, J., Qin, A., Tang, B. Z., Aroylacetylene-based amino-yne click polymerization toward nitrogen-containing polymers. Macromolecules, 2020, 53(7): 2516-2525.

[17]     邱欢, 李瑶, 白天闻, 凌君, 两仪聚合——拓扑结构聚合物合成新方法. 高分子学报, 2019, 50(11): 1133-1145.

[16]     Yang, Z., Bai, T., Ling, J., Shen, Y., Hydroxyl‐tolerated polymerization of N‐phenoxycarbonyl α‐amino acids: A simple way to polypeptides bearing hydroxyl groups. Journal of Polymer Science Part A: Polymer Chemistry, 2019, 57(8): 907-916.

[15]     Xu, H., Bai, T., Chen, H., Guo, F., Xi, J., Huang, T., Cai, S., Chu, X., Ling, J., Gao, W., Low-cost AlCl3/Et3NHCl electrolyte for high-performance aluminum-ion battery. Energy Storage Materials, 2019, 17: 38-45.

[14]     Wang, J., Bai, T., Chen, Y., Ye, C., Han, T., Qin, A., Ling, J., Tang, B. Z., Palladium/benzoic acid-catalyzed regio-and stereoselective polymerization of internal diynes and diols through C(sp3)-H activation. ACS Macro Letters, 2019, 8(9): 1068-1074.

[13]     Liu, S., Bai, T., Ni, K., Chen, Y., Zhao, J., Ling, J., Ye, X., Zhang, G., Biased Lewis pairs: A general catalytic approach to ether‐ester block copolymers with unlimited ordering of sequences. Angewandte Chemie International Edition, 2019, 58(43): 15478-15487.

[12]     Li, Z., Yang, Z., Bai, T., Ling, J., One-step synthesis and regioselective polymerization of Nα, Nδ-bisphenoxycarbonyl-L-ornithine. Polymer Chemistry, 2019, 10(9): 1062-1066.

[11]     Cai, S., Bai, T., Chen, H., Fang, W., Xu, Z., Lai, H., Huang, T., Xu, H., Chu, X., Ling, J., Heavy water enables high-voltage aqueous electrochemistry via the deuterium isotope effect. The Journal of Physical Chemistry Letters, 2019, 11(1): 303-310.

[10]     Zhu, C. N., Bai, T., Wang, H., Bai, W., Ling, J., Sun, J. Z., Huang, F., Wu, Z. L., Zheng, Q., Single chromophore-based white-light-emitting hydrogel with tunable fluorescence and patternability. ACS Applied Materials & Interfaces, 2018, 10(45): 39343-39352.

[9]       Zheng, B., Bai, T., Tao, X., Schlaad, H., Ling, J., Identifying the hydrolysis of carbonyl sulfide as a side reaction impeding the polymerization of N-substituted glycine N-thiocarboxyanhydride. Biomacromolecules, 2018, 19(11): 4263-4269.

[8]       Tao, X., Zheng, B., Bai, T., Li, M.-H., Ling, J., Polymerization of N-substituted glycine N-thiocarboxyanhydride through regioselective initiation of cysteamine: a direct way toward thiol-capped polypeptoids. Macromolecules, 2018, 51(12): 4494-4501.

[7]       Chen, X. Q., Yao, X., Bai, T., Ling, J., Xiao, W. J., Wang, J., Wu, S. C., Liu, L. N., Xie, G., Li, J., Donor-acceptor photovoltaic polymers based on 1, 4‐dithienyl‐2, 5‐dialkoxybenzene with intramolecular noncovalent interactions. Journal of Polymer Science Part A: Polymer Chemistry, 2018, 56(7): 689-698.

[6]       Zhang, J., Zhang, M., Bai, T., Ni, X., Shen, Z., Synthesis and characterization of heterobimetallic organo rare earth complexes bearing aryloxide-N-heterocyclic carbene ligands. Journal of Organometallic Chemistry, 2017, 843: 1-6.

[5]       Xie, Z., Ge, J., Zhang, H., Bai, T., He, S., Ling, J., Sun, H., Zhu, Q., A highly selective two-photon fluorogenic probe for formaldehyde and its bioimaging application in cells and zebrafish. Sensors and Actuators B: Chemical, 2017, 241: 1050-1056.

[4]       Tao, X., Zheng, B., Bai, T., Zhu, B., Ling, J., Hydroxyl group tolerated polymerization of N-substituted glycine N-thiocarboxyanhydride mediated by aminoalcohols: a simple way to α-Hydroxyl-ω-aminotelechelic polypeptoids. Macromolecules, 2017, 50(8): 3066-3077.

[3]       Shi, Y., Bai, T., Bai, W., Wang, Z., Chen, M., Yao, B., Sun, J. Z., Qin, A., Ling, J., Tang, B. Z., Phenol‐yne Click Polymerization: An efficient technique to facilely access regio- and stereoregular poly(vinylene ether ketone)s. Chemistry - A European Journal, 2017, 23(45): 10725-10731.

[2]       Li, Y., Bai, T., Li, Y., Ling, J., Branched polytetrahydrofuran and poly (tetrahydrofuran‐co‐ε‐caprolactone) synthesized by Janus polymerization: A novel self‐healing material. Macromolecular Chemistry and Physics, 2017, 218(3): 1600450.

[1]       He, B., Su, H., Bai, T., Wu, Y., Li, S., Gao, M., Hu, R., Zhao, Z., Qin, A., Ling, J., Spontaneous amino-yne click polymerization: a powerful tool toward regio-and stereospecific poly (β-aminoacrylate)s. Journal of the American Chemical Society, 2017, 139(15): 5437-5443.

授权专利：

一种超支化聚四氢呋喃的合成方法, 2016-8-18, 中国, ZL201610692611.6

获奖情况：

2023年 第十四届浙江省大学生化学竞赛省二等奖